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The question whether matter is atomistically constituted or continuous is already present in the writings of Greek philosophers. C.. We can echo here what Maxwell said in a popular lecture, if we modify the number of centuries: “We do not know much about the science organisation of Thrace twenty-three centuries ago, or of the machinery then employed for diffusing an interest in physical research. There were men, however, in those days, who devoted their lives to the pursuit of knowledge with an ardour worthy of the most distinguished members of the British Association; and the lectures in which Democritus explained the atomic theory to his fellow-citizens of Abdera realised, not in golden opinions only, but in golden talents, a sum hardly equalled even in America”.

89, 714 (1884). 28. J. W. Gibbs: Elementary principles in statistical mechanics, developed with special reference to the rational foundations of thermodynamics , Yale University Press (1902). 29. M. J. Klein: “The Development of Boltzmann’s Statistical Ideas”, in The Boltzmann Equation. Theory and Application, p. 53-106, E. G. D. Cohen and W. , Springer-Verlag, Vienna (1973). 30. G. Helm: Die Energetik nach ihrer geschichtlichen Entwicklung, Veit, Leipzig (1898). 31. J. W. Gibbs: “On the equilibrium of heterogeneous substances”, in The Scientific Papers of J.

He soon realized, however (footnote to paper [23]), that it was necessary to make a “not improbable” assumption for real bodies made of molecules that are moving because they possess “the motion that we call heat”. This assumption, according to which the coordinates and the velocities of the molecules take on, in an equilibrium state, all values compatible with the assigned total energy of the gas, became later familiar as ergodic hypothesis, the name given to it by Paul and Tatiana Ehrenfest [24].

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